GBW10010a大米标准物质复(研)制及数据特征     

杨榕  顾铁新  潘含江  刘妹  周国华 《岩矿测试》2020,39(6):866-877

随着我国对生态文明建设的重视，自然资源综合调查势在必行，对生物标准物质亦提出了新的需求。当前相关调研工作已经大面积开展，自然资源综合调查、农产品与食品安全评价都需要对生物样品元素组成进行准确测试，需要以生物标准物质作为生物成分测试量值比对和溯源的基础，因此对生物基体标准物质的需求量大幅增加。大米作为主要粮食之一，其食品安全日益受到重视，对大米中的化学成分进行准确的分析测试具有重要的现实意义，因而对大米标准物质的需求量尤为突出，但目前大米成分分析标准物质已供不应求。本文严格按照《标准物质定值的通用原则及统计学原理》（JJF 1343—2012）和《地质分析标准物质的研制》（JJF 1646—2017）等相关规范要求，开展了GBW10010a大米成分分析标准物质的复（研）制工作，包括样品采集、加工制备、均匀性检验、稳定性检验、多家实验室协作定值测试及不确定度评定等关键环节。结果表明：本次复（研）制的大米标准物质定值成分多样、量值准确可靠，符合国家一级标准物质的要求。GBW10010a共定值54项主微量元素，包括Ag、Al、As、B、Ba、Be、Bi、Ca、Cd、Ce、Co、Cr、Cs、Cu、Dy、Er、Eu、Fe、Gd、Ge、Hg、Ho、K、La、Li、Ho、Mg、Mn、Mo、N、Na、Nb、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Sc、Se、Si、Sm、Sr、Tb、Th、Tl、Tm、U、V、Y、Yb、Zn，其中的39项元素给出了标准值及不确定度，包括Ag、Al、As、B、Ba、Ca、Cd、Ce、Co、Cs、Cu、Dy、Er、Fe、Hg、K、Li、Mg、Mn、Mo、N、Na、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Se、Si、Sm、Sr、Tb、Tl、Y、Yb、Zn；15项元素提供参考值，包括Be、Bi、Cr、Eu、Gd、Ge、Ho、Ho、La、Nb、Sc、Th、Tm、U、V。与原有GBW10010大米标准物质相比较，GBW10010a中As、Cd、Co、Cr、Cu、Hg、Mn、Mo、Ni、Zn等重金属元素含量显著下降，其中Cd、Cu、Zn降幅较大，分别下降约39%、43%、38.7%，一定程度上反映了农田生态环境的改善。本批标准物质定值元素总数量增加了6项，新增定值元素Ag、Nb（Nb给出参考值），并且各项元素不确定度范围整体上有所缩小，如Al、Cd、Cu、Fe、K、Mg、Mo、Na、P、Pb、Se、Zn等对生物易有影响的重要元素，表明了地质分析测试方法技术的进步及定值水平的提高。本批标准物质定值元素涵盖了具有生物效应的大部分主微量元素，适用于农业生态环境地球化学调查与评价、生物样品测试、农产品质量与食品安全评价样品测试时的分析仪器校正、分析方法评价和分析质量监控等多个领域。  相似文献   

南昌商业中心深基坑工程组合支护技术          下载免费PDF全文

谢秋明  张青平 《探矿工程》2020,47(9):75-80,96

以南昌市一商业中心深基坑支护工程实例为背景，通过分析周边环境、地质条件、开挖深度,在保证安全的前提下，充分利用各种因素降低基坑支护造价。在地下水控制上，合理确定坑外地下水位控制标高，采用截水、降水的组合形式。基坑支护采用组合支护结构，在不同部位分别采用土钉墙、锚拉式排桩的支护形式；支护结构上，下部采用不同结构类型的组合。通过设计方案比较与优化，做到安全适用、经济合理。  相似文献   

Subaquatic slope instabilities: The aftermath of river correction and artificial dumps in Lake Biel (Switzerland)     

Nathalie Dubois  Love Råman Vinnå  Marvin Rabold  Michael Hilbe  Flavio S. Anselmetti  Alfred Wüest  Laetitia Meuriot  Alice Jeannet  Stéphanie Girardclos 《Sedimentology》2020,67(2):971-990

River engineering projects are developing rapidly across the globe, drastically modifying water courses and sediment transfer. Investigation of the impact of engineering works focuses usually on short-term impacts, thus a longer-term perspective is still missing on the effects that such projects have. The ‘Jura Water Corrections’ – the largest river engineering project ever undertaken in Switzerland – radically modified the hydrological system of Lake Biel in the 19th and 20th Century. The deviation of the Aare River into Lake Biel more than 140 years ago, in 1878, thus represents an ideal case study to investigate the long-term sedimentological impacts of such large-scale river rerouting. Sediment cores, along with new high-resolution bathymetric and seismic reflection datasets were acquired in Lake Biel to document the consequences of the Jura Water Corrections on the sedimentation history of Lake Biel. Numerous subaquatic mass transport structures were detected on all of the slopes of the lake. Notably, a relatively large mass transport complex (0·86 km²) was observed on the eastern shore, along the path of the Aare River intrusion. The large amount of sediment delivered by the Aare River since its deviation into the lake likely caused sediment overloading resulting in subaquatic mass transport. Alternatively, the dumping since 1963 in a subaquatic landfill of material excavated during the second phase of river engineering, when the channels flowing into and out of Lake Biel were widened and deepened, might have triggered the largest mass transport, dated to 1964 or 1965. Additional potential triggers include two nearby small earthquakes in 1964 and 1965 (M_W 3·9 and 3·2, respectively). The data for this study indicate that relatively large mass transports have become recurrent in Lake Biel following the deviation of the Aare River, thus modifying hazard frequency for the neighbouring communities and infrastructure.  相似文献   

近15a陕西省植被时空变化与影响因素分析          下载免费PDF全文

岳辉  刘英 《干旱区地理》2019,42(2):314-323

利用2000—2014年MODIS/NDVI时间序列数据，采用栅格像元趋势分析、稳定性评价的方法，研究了陕西省近15 a植被的时空变化特征和规律；利用Hurst指数对陕西省植被未来变化趋势进行了预测；并利用相关性分析法分析了NDVI与年均温度和降雨量的关系。结果表明，2000年、2015年陕西省NDVI均值分别为0.4273、0.4942， 15 a来增加了0.067，增长了16.0%，其中陕北地区NDVI增加明显，关中部分地区出现负增长，陕南地区NDVI总体依旧维持在较高水平。陕西省植被变化趋势具有明显的空间差异性，全省植被未变化的占52.0 %，改善部分占44.27 %，退化部分占3.73%，说明15 a间陕西省植被覆盖改善面积大于退化面积，植被状况有所改善；其中陕北地区植被呈明显改善区域面积较大，关中地区植被覆盖面积有所减少，陕南地区植被变化幅度较小。陕西省植被稳定区域占50%以上（0 0.2)，说明15a间陕西省植被较为稳定，变化程度不大；其中陕西省植被最稳定地区主要集中在陕南、延安南部，榆林部分、西安、渭南少部地区变化幅度较大。Hurst指数分析表明陕西省44.54%面积的植被未来有可能面临退化，主要分布在陕北和关中地区的北部，植被未来有可能退化也有可能改善的面积占49.78%，主要分布在延安和陕南地区。陕西省近15 a气温和降水量总体呈增加趋势，增加速率分别为0.48 ℃·(10 a)-1和69.5 mm ( a)-1；相关性分析结果表明，年均降雨量是影响NDVI的主要气象因子，同时陕西省植被变化也受到了退耕还林还草、防沙治沙、生态政治等人为因素的影响。  相似文献   

非等间距GM(1,1)模型的总体最小二乘算法及其病态问题     

陶武勇  花向红  鲁铁定  陈西江  张伟 《大地测量与地球动力学》2019,39(1):45-50

在非等间距GM(1,1)模型中，系数矩阵中有无误差的常数项和有误差的随机项，并且系数矩阵与观测向量误差同源，即系数矩阵与观测向量中有相同的元素存在，这些相同元素应该有相同的改正数，为此本文推导了一种适合非等间距GM(1,1)模型求解的总体最小二乘算法。同时，考虑到非等间距GM(1,1)模型中存在病态问题时影响总体最小二乘计算结果的稳定性，提出对系数矩阵常数列乘以某一常数的方法，以改善病态问题。  相似文献   

Stability analysis of shotcrete supported crown of NATM tunnels with discontinuity layout optimization          下载免费PDF全文

Yiming Zhang  Xiaoying Zhuang  Roman Lackner 《国际地质力学数值与分析法杂志》2018,42(11):1199-1216

For tunnel constructed by New Austrian Tunnelling Method, the crown is the upper part of tunnel section, constructed during excavation process and supported by shotcrete. The stability of the crown has great influence on the safety of tunnel itself and the buildings above, which correlates, among others, with geometrical setup of tunnel and material properties of shotcrete and soil/rock. In this paper, aiming at analyzing the stability of shotcrete supported crown, a recently presented numerical method discontinuity layout optimization is adopted, which introduces a great amount of potential discontinuities cross over one another and provides a wide search space for efficient upper limit analysis. In the analysis, a well‐established hydration model of cementitious material is implemented for accounting the hydration of shotcrete. Then assumptions based on convergence‐confinement method are used for accounting the 3‐dimensional effect in 2‐dimensional analysis, finally providing time‐space–dependent assessments of stability of shotcrete supported crown.  相似文献   

How deep can forest vegetation cover extend their hydrological reinforcing contribution?          下载免费PDF全文

Elyas Hayati  Ehsan Abdi  Mohsen Mohseni Saravi  John L. Nieber  Baris Majnounian  Giovanni B. Chirico 《水文研究》2018,32(16):2570-2583

An experimental campaign was set up to quantify the contribution of evapotranspiration fluxes on hillslope hydrology and stability for different forest vegetation cover types. Three adjacent hillslopes, respectively, covered by hardwood, softwood, and grass were instrumented with nine access tubes each to monitor soil water dynamics at the three depths of 30, 60, and 100 cm, using a PR2/6 profile probe (Delta‐T Devices Ltd) for about 6 months including wet periods. Soil was drier under softwood and wetter under grass at all the three depths during most of the monitoring period. Matric suction derived via the soil moisture measurements was more responsive to changes in the atmospheric conditions and also recovered faster at the 30 cm depth. Results showed no significant differences between mean matric suction under hardwood (101.6 kPa) with that under either softwood or grass cover. However, a significant difference was found between mean matric suction under softwood (137.5 kPa) and grass (84.3 kPa). Results revealed that, during the wettest period, the hydrological effects from all three vegetation covers were substantial at the 30 cm depth, whereas the contribution from grass cover at 60 cm (2.0 kPa) and 100 cm (1.1 kPa) depths and from hardwood trees at 100 cm depth (1.2 kPa) was negligible. It is surmised that potential instability would have occurred at these larger depths along hillslopes where shallow hillslope failures are most likely to occur in the region. The hydrological effects from softwood trees, 8.1 and 3.9 kPa, were significant as the corresponding factor of safety values showed stable conditions at both depths of 60 and 100 cm, respectively. Therefore, the considerable hydrological reinforcing effects from softwood trees to the 100 cm depth suggest that a hillslope stability analysis would show that hillslopes with softwood trees will be stable even during the wet season.  相似文献   

青藏铁路沿线不同类型挡沙墙阻沙率     

杨印海  薛春晓  石龙  李凯崇  孔令伟  张芳 《中国沙漠》2020,40(1):173-178

基于风洞试验对青藏铁路沿线不同类型防沙措施防沙效果进行模拟研究，探讨了不同类型挡沙墙的防沙效果。结果表明：挂板式、轨枕式和箱式挡沙墙输沙率随高度基本呈递增缓变型趋势，最大输沙率低于20%；铃铛式和高立式聚乙烯（PE）网挡沙墙随高度呈递减陡降型趋势，距地表6~8 cm处为转折点，转折点以上输沙率随高度增大急剧减小，转折点以下输沙率随高度变化较为平缓，最大输沙率低于50%。随着风速的增大，各挡沙墙的阻沙率呈递减趋势：挂板式和轨枕式挡沙墙对风速的敏感性最弱，整体阻沙效果较优，可大范围推广；箱式挡沙墙对风速的敏感性较弱，建议在风速18 m·s^-1以下的地区使用；PE网挡沙墙防沙效果对风速的敏感性最强，建议在风速10 m·s^-1以下的地区使用。  相似文献   

Effect of 2D spatial variability on slope reliability: A simplified FORM analysis     

《地学前缘(英文版)》2018,9(6):1631-1638

To meet the high demand for reliability based design of slopes, we present in this paper a simplified HLRF(Hasofere Linde Rackwitze Fiessler) iterative algorithm for first-order reliability method(FORM). It is simply formulated in x-space and requires neither transformation of correlated random variables nor optimization tools. The solution can be easily improved by iteratively adjusting the step length. The algorithm is particularly useful to practicing engineers for geotechnical reliability analysis where standalone(deterministic) numerical packages are used. Based on the proposed algorithm and through direct perturbation analysis of random variables, we conducted a case study of earth slope reliability with complete consideration of soil uncertainty and spatial variability.  相似文献   

Probabilistic stability analyses of undrained slopes by 3D random fields and finite element methods     

《地学前缘(英文版)》2018,9(6):1657-1664

A long slope consisting of spatially random soils is a common geographical feature. This paper examined the necessity of three-dimensional(3 D) analysis when dealing with slope with full randomness in soil properties. Although 3 D random finite element analysis can well reflect the spatial variability of soil properties, it is often time-consuming for probabilistic stability analysis. For this reason, we also examined the least advantageous(or most pessimistic) cross-section of the studied slope. The concept of"most pessimistic" refers to the minimal cross-sectional average of undrained shear strength. The selection of the most pessimistic section is achievable by simulating the undrained shear strength as a 3 D random field. Random finite element analysis results suggest that two-dimensional(2 D) plane strain analysis based the most pessimistic cross-section generally provides a more conservative result than the corresponding full 3 D analysis. The level of conservativeness is around 15% on average. This result may have engineering implications for slope design where computationally tractable 2 D analyses based on the procedure proposed in this study could ensure conservative results.  相似文献